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Publications – Nachwuchsgruppe Gutmann – Technische Universität Darmstadt
Back to tab navigation. DR-UV-vis and XPS demonstrate that the oxidation state and the Rh—Rh single bond in the dirhodium node are maintained during the ligand substitution process. For reproduction of material from all other RSC journals and books: This may take some time to load. Go to our Instructions for using Copyright Clearance Center page for details.
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The individual lamellae of the dirhodium-bdc frameworks are stacked as parallel sheets, which are randomly oriented or slightly ordered. Jump to main content. Information about reproducing material from RSC articles with different licences is available on our Permission Requests page. For reproduction of material from PPS: Authors contributing to RSC publications journal articles, books or book chapters do not need to formally request permission to reproduce material contained in this article provided that gutmxnn correct acknowledgement is given with the reproduced material.
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Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study J. For reproduction of material from PCCP: XX is the XXth reference in the list of references. Catalytically active dirhodium sheet-like coordination polymers are synthesized from their precursors via ligand exchange.
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Residual trifluoroacetate species are investigated by quantitative 19 F MAS NMR which further reflects the configuration ghtmann trifluoroacetate in the obtained Rh 2 -bdc Tfand defects in the structure. The stability and reusability of the catalysts are verified by TG-DTA measurements and leaching tests. Jump to site search.
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